세션명 | 기능성 고분자 |
---|---|
발표장 | 제5회장 (205-206) |
논문코드 | 1O5-1 |
발표일 | 2018-10-11 |
발표시간 | 17:30-17:50 |
논문제목 | Fabrication of Various Sensor Systems Using Polydiacetylenes |
발표자 | 신재섭 |
발표자 소속 | 충북대학교 |
저자 | 신민재, 김민희1, 신재섭1,† |
소속 | 세명대학교; 1충북대학교 |
논문초록 | Polydiacetylenes (PDAs) have a special character in which their color changes from blue to red by outer stimuli. 1) A glucose sensor was fabricated using a PDA. H2O2 formed by the reaction between glucose and glucose oxidase functioned as the initiator. The glucose concentration could be detected that turns the solution to blue. 2) PDA and poly(sodium 4-styrene-sulfonate) (PSS) were alternately stacked to form a layer-by-layer (LBL) film. The formed-film sensor showed higher sensitivity than the vesicle solution. 3) The noble vesicular system of PDA showed a red shift by the permeation through the vesicular layers from within the vesicle. 4) The thermal chromatic sensitivity of PDAs with 10,12-pentacosadiynoic acid (PCDA) derivatives which have a hydroxyl group (HEEPCDA) were investigated. The vesicle solution with polymerized HEEPCDA exhibited a reversible chromatic response during the heating and cooling cycle in D2O, but not in H2O. |